Grande Mathilde XO This page first published: Jul 4, 2004 · Updated: Oct 4, 2020 · by CooksInfo. Copyright © 2021 · This post may contain affiliate links · This blog generates income via ads · Grande Mathilde XO is an orange liqueur made from cognac that has been aged for at least 8 years. It is made by Gabriel & Andreu in France near Cognac, and sold in a tall, clear glass bottle.